No, jump into Remote Desktop.
Start > Run > control panel [enter]
Open IIS
In the IP feild make sure that only the default IIS site has "All unassigned" as the IP value.
Go to the profile with the static IP.
Right click > Properties > Advanced
Where is saids "multiple identies for this website"
Make sure you have 222.222.222.222 where that is your unique IP for this site listed in there with the tcp port as 80. Leave host header value blank.
[OK] everything out.
Go to
http://222.222.222.222, please CTRL + F5 and you should see the site your looking for.